You have to drop constraint and recreate it:
alter table Persion drop CONSTRAINT <constraint_name>
alter table Persion add primary key (persionId,Pname,PMID)
Edit:
you can find the constraint name by using the query below:
select OBJECT_NAME(OBJECT_ID) AS NameofConstraint
FROM sys.objects
where OBJECT_NAME(parent_object_id)='Persion'
and type_desc LIKE '%CONSTRAINT'