You can interact with Simple AD in the same way you do with any other LDAP ( Lightweight Directory Access Protocol) server. You need to be within the VPC but the following code works.
Example
/tmp/username.ldif
dn: CN=Test User,CN=Users,DC=ad,DC=example,DC=org changeType: modify add: objectClass objectClass: ldapPublicKey dn: CN=Test User,CN=Users,DC=ad,DC=example,DC=org changeType: modify add: sshPublicKey sshPublicKey: ssh-rsa ....
ldbmodify --verbose --url "ldap://ad.example.org" --user "SIMPLEAD_USERNAME" --password 'SIMPLE_AD_PASSWORD' /tmp/username.ldif
For further details you can click on the below link.
https://github.com/localytics/chef-sssd/blob/master/GETTING_STARTED.md